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Coherent Spin Dynamics of Electrons and Holes in CsPbBr 3 Colloidal Nanocrystals

Abstract : The spin dynamics in CsPbBr 3 lead halide perovskite nanocrystals are studied by picosecond pump−probe Faraday rotation in an external magnetic field. Coherent Larmor precession of electrons and holes with spin dephasing times of ∼600 ps is detected in a transversal magnetic field. The longitudinal spin relaxation time in weak magnetic fields reaches 80 ns at a temperature of 5 K. In this regime, the carrier spin dynamics is governed by nuclear spin fluctuations characterized by an effective hyperfine field strength of 25 mT. The Landéfactors determining the carrier Zeeman splittings are g e = +1.73 for electrons and g h = +0.83 for holes. A comparison with a CsPbBr 3 polycrystalline film and bulk single crystals evidences that the spatial confinement of electrons and holes in the nanocrystals only slightly affects their g factors and spin dynamics.
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Submitted on : Friday, October 1, 2021 - 9:42:14 AM
Last modification on : Monday, December 6, 2021 - 4:20:03 PM

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Philipp Grigoryev, Vasilii Belykh, Dmitri Yakovlev, Emmanuel Lhuillier, Manfred Bayer. Coherent Spin Dynamics of Electrons and Holes in CsPbBr 3 Colloidal Nanocrystals. Nano Letters, American Chemical Society, 2021, ⟨10.1021/acs.nanolett.1c03292⟩. ⟨hal-03360866⟩

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